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Bachovchin, William Walter (1977) The Mechanism of Action of Adenosylcobalamin: I. 3-Fluoro-1, 2-Propanediol Dehydrase - Mechanistic Implications. II. Glycerol and Other Substrate Analogues as Substrates and Inactivators for Propanediol Dehydrase. Kinetics, Stereospecificity and Mechanism. III. The Involvement of a 5'-Deoxyadenosine Intermediate Containing Three Equivalent Hydrogens in the Mechanism of Glycerol Inactivation of Propanediol Dehydrase Holoenzyme. IV. Hydrogen Transfer from Enzyme-Bound Adenosylcobalamin as a Partial Rate Limiting Step in Catalysis. Dissertation (Ph.D.), California Institute of Technology. doi:10.7907/8fy8-dk59. https://resolver.caltech.edu/CaltechTHESIS:09262025-201250378 |