Cyclic Polyolefins via Ring-Expansion Metathesis Polymerization

Author: Edwards, Julian Peter

Year: 2018

Degree: Dissertation (Ph.D.)

Advisor: Grubbs, Robert H.

Committee Members: Davis, Mark E.; Stoltz, Brian M.; Dougherty, Dennis A.; Grubbs, Robert H.

Option: Chemistry

DOI: 10.7907/kmh1-y153

Abstract

The synthesis of cyclic polyolefins prepared using a supported, molecular ring-expansion metathesis polymerization catalyst is described. The synthesis of the catalysts, themselves, is described in detail. Additionally, thorough physical characterization of cyclic polymers with comparison to linear polymer analogues is reported.

Files

• [Chapter 1 - Final.pdf](/10938/01/Chapter 1 - Final.pdf) (application/pdf)
• [Chapter 2 - Final.pdf](/10938/07/Chapter 2 - Final.pdf) (application/pdf)
• [Chapter 3 - Final .pdf](/10938/24/Chapter 3 - Final .pdf) (application/pdf)
• [Chapter 4 - Final .pdf](/10938/25/Chapter 4 - Final .pdf) (application/pdf)
• [Chapter 5 - Final.pdf](/10938/26/Chapter 5 - Final.pdf) (application/pdf)
• [Appendix A.pdf](/10938/42/Appendix A.pdf) (application/pdf)
• [Appendix B.pdf](/10938/43/Appendix B.pdf) (application/pdf)
• [Dissertation - Final.pdf](/10938/44/Dissertation - Final.pdf) (application/pdf)
• [Dissertation - Final.pdf](/10938/66/Dissertation - Final.pdf) (application/pdf)